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Gold Purity

Because of the softness of pure (24k) gold, it is usually alloyed with base metals for use in jewelry, altering its hardness and ductility, melting point, color and other properties. Alloys with lower cartage, typically 22k, 18k, 14k or 10k, contain higher percentages of copper, or other base metals or silver or palladium in the alloy. Copper is the most commonly used base metal, yielding a redder color. 18k gold containing 25% copper is found in antique and Russian jewelery and has a distinct, though not dominant, copper cast, creating rose gold. Fourteen carat gold-copper alloy is nearly identical in color to certain bronze alloys, and both may be used to produce police and other badges. Blue gold can be made by alloying with iron and purple gold can be made by alloying with aluminum, although rarely done except in specialized jewelry. Blue gold is more brittle and therefore more difficult to work with when making jewelry. Fourteen and eighteen carat gold alloys with silver alone appear greenish-yellow and are referred to as green gold. White gold alloys can be made with palladium or nickel. White 18 carat gold containing 17.3% nickel, 5.5% zinc and 2.2% copper is silver in appearance. Nickel is toxic, however, and its release from nickel white gold is controlled by legislation in Europe. Alternative white gold alloys are available based on palladium, silver and other white metals (World Gold Council), but the palladium alloys are more expensive than those using nickel. High-carat white gold alloys are far more resistant to corrosion than are either pure silver or sterling silver. The Japanese craft of Mokume-gane exploits the color contrasts between laminated colored gold alloys to produce decorative wood-grain effects.

The Relationship between Purity, Carats and Fineness

 

The purity of gold is expressed in carats, often abbreviated to ‘ct’ of ‘K’ in the USA and some other countries. Pure gold has a purity of 24 carats. Various other purities exist that are measured relative to 24 carats. These are summarized in the table below.

Table 1. The relationship between gold content (by weight), its carat rating and hallmark rating for standard gold alloys.

Purity

Gold content (wt. %)

Fineness

24 carat gold

99+

990

22 carat gold

91.6

916

18 carat gold

75.0

750

14 carat gold

58.5

585

9 carat gold

37.5

375

An alternative method of expressing purity is ‘fineness’. This expresses the purity of gold in parts per 1000.

Gold may be alloyed with other metals such as silver, copper, zinc or silicon to produce purities less than 24 carat. Silver and copper and most commonly used alloying elements for gold. Pure gold is too soft to be able to be used for jewellery.

The metal chosen as an alloying element my influence properties such as workability and colour of the resultant gold alloy.

The purity of the gold is ‘marked’ onto jewellery by stamping or laser engraving. This acts a quality control stamp. Often this is done after the alloy is tested by a qualified testing laboratory or facility. Depending on which country the gold is produced, the caratage or fineness may be stamped into the item of jewellery.

According to the International Hallmarking Convention, there is a “no negative tolerance” policy. This means that a gold alloy determined to consist of 749 parts of gold per 1000 would not qualify for a 750 quality mark.

Methods used to assay or test the purity of gold include:

·         Inductively Couple Plasma Spectrometry (ICP)

·         X-Ray Fluorescence

·         Fire Assay

·         Touchstone



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